TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]NEODYMIUM (III)

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]NEODYMIUM (III) - Names and Identifiers

Name	Tris[N,N-bis(trimethylsilyl)amide]neodymium(III)
Synonyms	)amide]neodymium(III) Tris[N,N-bis(trimethylsilyl)amide]neodymium Tris,N-bis(trimethylsilyl)amideeodymium(III) Tris[N,N-bis(trimethylsilyl)amide]neodymium(Ⅲ) Tris[N,N-bis(trimethylsilyl)amide]neodymium(III) TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]NEODYMIUM (III) 1,1,1-Trimethyl-N-(trimethylsilyl)silanamine neodymium(III) salt
CAS	148274-47-9

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]NEODYMIUM (III) - Physico-chemical Properties

Molecular Formula	C18H54N3NdSi6
Molar Mass	625.39
Melting Point	156-159°C(lit.)
Flash Point	36°F
Sensitive	Air & Moisture Sensitive
MDL	MFCD03427089

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]NEODYMIUM (III) - Risk and Safety

Risk Codes	R11 - Highly Flammable R14/15 - R34 - Causes burns
Safety Description	S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S7/8 -
UN IDs	UN 3396 4.3/PG 2
WGK Germany	3
Hazard Class	4.1
Packing Group	III

TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]NEODYMIUM (III) - Introduction

Tris[N,N-bis(trimethylsilyl)amide] neodium (III) is a chemical complex with the formula Nd[N(Si(CH3)3)2]3. Its properties are as follows:

-Appearance: White solid
-Melting point: About 300-350 ° C
-Solubility: Soluble in non-polar organic solvents such as benzene and toluene
-Stability: stable in the air, but easy to get wet under moisture

Tris[N,N-bis(trimethylsilyl)amide] neodium (III) is mainly used in organic synthesis and coordination chemistry. It can be used as a reagent for organolithium compounds to react with organometallic compounds. In addition, it can also be used in the preparation of coordination polymers, liquid crystals and oxide materials.

Tris[N,N-bis] neodium (III) can be prepared by the following steps:

1. NdCl3 · 6H2O reacts with trimethylchlorosilane in anhydrous toluene to generate NdCl3(Si(CH3)3)3.

2. The anhydrous toluene was distilled off and recrystallized with a dry non-polar organic solvent to finally obtain Tris[N,N-bis(trimethylsilyl)amide] neodium (III).

For safety information, Tris[N,N-bis(trimethylsilyl)amide] neodium (III) should be stored in a dry place and protected from moisture. Wear protective gloves and eye protection during operation, and take care to avoid inhaling dust or touching skin. Proper laboratory safety practices should be observed during handling or storage.

Last Update：2024-04-10 22:29:15